Yakisobapanman

Yakisobapanman's head is based on bread and fried noodles. He wears a brown hat, an orange outfit with the letter Y, a green bandana, a yellow belt, and red boots and gloves.
Yakisobapanman can be seen in horseback riding with his sister Yakisobakasu. He attacks with sharp spatulas that act as boomerangs. He throws his weapon cutting anything in it's path, then returning to it's owner.
Yakisobapanman is debuted in January 22, 1999, on the episode Anpanman and Yakisobapanman. His sister did not appear until an episode in the next month, called Anpanman and Yakisobakasu. Afterwards, both made more appearances in the anime, establishing them as popular minor characters.

(Source: Anpanman Wiki)